Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex
Open Access
- 30 June 2012
- journal article
- Published by European Journal of Chemistry in European Journal of Chemistry
- Vol. 3 (2), 211-213
- https://doi.org/10.5155/eurjchem.3.2.211-213.594
Abstract
The title compound, C32H44Br2CuN4O2S2, was synthesized from 4-bromo-N-(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P-1 (no. 2) with unit cell dimensions of a = 8.519(10) Å, b = 16.64(2) Å, c = 25.78(4) Å, α = 77.11(3)o, β = 85.59(3)o, γ = 89.46(2)o , Z = 4 and V = 795.8(6) Å3. The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.Keywords
This publication has 31 references indexed in Scilit:
- Mesomorphic behaviour of N-benzoyl-N′-aryl thioureas liquid crystalline compoundsJournal of Molecular Structure, 2011
- Synthesis, spectroscopic characterization, crystal structure and pharmacological properties of some novel thiophene-thiourea core derivativesEuropean Journal of Chemistry, 2010
- Synthesis, characterization and antibacterial activity of nickel (II) and copper (II) complexes of N-(alkyl(aryl)carbamothioyl)-4-nitrobenzamideEuropean Journal of Chemistry, 2010
- Synthesis and Characterization ofN-(2,2-Diphenylacetyl)-N′-Substituted Thiourea Derivatives: The Crystal Structure ofN-(2,2-Diphenylacetyl)-N′-(4-chloro phenyl)-thioureaPhosphorus, Sulfur, and Silicon and the Related Elements, 2009
- N-1-Naphthyl-3-oxobutanamide in Heterocyclic Synthesis: A Facile Synthesis of Nicotinamide, Thieno[2,3-b]pyridine, and Bi- or Tricyclic Annulated Pyridine Derivatives Containing Naphthyl MoietyPhosphorus, Sulfur, and Silicon and the Related Elements, 2009
- Antimicrobial Activity of Some Thiourea Derivatives and Their Nickel and Copper ComplexesMolecules, 2009
- Synthesis, characterization and antimicrobial activities of transition metal complexes of N,N -dialkyl- N′ -(2-chlorobenzoyl)thiourea derivativesJournal of Coordination Chemistry, 2006
- New chemistry with old ligands: N-alkyl- and N,N-dialkyl-N′-acyl(aroyl)thioureas in co-ordination, analytical and process chemistry of the platinum group metalsCoordination Chemistry Reviews, 2001
- Synthesis, characterisation and coordination chemistry of novel chiral N,N-dialkyl-N ′-menthyloxycarbonylthioureas. Crystal and molecular structures of N,N-diethyl-N ′-(−)-(3R)-menthyloxycarbonylthiourea and cis-(S,S)-[Pt(L)Cl(DMSO)] [where HL = N-(+)-(3R)-menthyloxycarbonyl-N′-morpholinothiourea or N-benzoyl-N′,N′-diethylthiourea]J. Chem. Soc., Dalton Trans., 2000
- Pesticidal activities of some 3-aryl-4-methylpyrazolo[3,4-b][1,5]benzodiazepines and 4-aryl-2-imino-5-methyl-1,3-thiazino[4,5-b][1,5]benzodiazepinesJournal of Agricultural and Food Chemistry, 1995