Superwetting Patterned Membranes with an Anisotropy/Isotropy Transition: Towards Signal Expression and Liquid Permeation
- 3 August 2020
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 59 (32), 13437-13443
- https://doi.org/10.1002/anie.202005030
Abstract
Superwetting membranes with responsive properties have attracted heightened attention because of their fine-tunable surface wettability. However, their functional diversity is severely limited by the "black-or-white" wettability transition. Herein, we describe a coating strategy to fabricate multifunctional responsive superwetting membranes with SiO2/octadecylamine patterns. The adjustable patterns in the responsive region are the key factor for functional diversity. Specifically, the coated part of the membrane displayed a superhydrophobicity/superhydrophilicity transition at different pH values, whereas the uncoated part exhibited invariant superhydrophilicity. On the basis of this anisotropy/isotropy transition, the membranes can serve as either responsive permeable membranes or signal-expression membranes, thus enabling the responsive separation and permeation of liquids with satisfactory separation efficiency (>99.90 %) and flux (ca. 60 L m(-2) h), as well as real-time liquid signal expression with alterable signals.Funding Information
- National Natural Science Foundation of China (51173099, 21788102)
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