Abstract
Thermophotovoltaics (TPVs), a heat recovery technique, is faced with low efficiency and power density. It has been proven that graphene helps add new functionalities to optical components and improve their performance for heat transfer. In this work, I study Near-field radiative heat transfer in TPVs based on a composite nanostructure composed of Indium Tin Oxide (ITO) sheet and a narrow bandgap photovoltaic cell made from Indium Arsenide (InAs). I introduce a new way to calculate nonradiative recombination (NR) and compare the performance with and without the NR being considered. By comparing graphene modulated on the emitter (G-E), on the receiver (G-R), and on both the emitter and the receiver (G-ER), I find the G-ER case can achieve the highest current density. However, constrained by the bandgap energy of the cell, this case is far lower than the G-E case when it comes to efficiency. After applying variant particle swarm optimization (VPSO) and dynamic optimization, the model is optimized up to 43.63% efficiency and 11 W/cm2 electric power at a 10 nm vacuum gap with a temperature difference of 600 K. Compared with before optimization, the improvement is 8.97% and 7.2 W/cm2, respectively. By analyzing the emission spectrum and the transmission coefficient, I find that after optimization the system can achieve higher emissivity above the bandgap frequency, thus achieving more efficient conversion of light to electricity. In addition, I analyze the influence of temperature difference by varying it from 300 K to 900 K, indicating the optimized model at a 900 K temperature difference can achieve 49.04% efficiency and 52 W/cm2 electric power. By comparing the results with related works, this work can achieve higher conversion efficiency and electric power after the optimization of relevant parameters. My work provides a method to manipulate the near-field TPV system with the use of a graphene-based emitter and promises to provide references in TPV systems that use low bandgap energy cells.