Terahertz Surface Emission from MoSe2 at the Monolayer Limit
- 29 September 2020
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 12 (42), 48161-48169
- https://doi.org/10.1021/acsami.0c13474
Abstract
Surface-charge region of bulk and monolayer MoSe2 is analyzed directly by terahertz (THz) surface emission spectroscopy in a non-destructive way. Both surface nonlinear optical polarization and surface field induced photocurrent contribute to the THz radiation in both bulk and monolayer MoSe2. The first THz emission mechanism is due to the surface optical rectification and the second one is due to the photo-generated carriers accelerated by the surface depletion field. The THz radiation contribution from the surface optical rectification is basically the same for both bulk and monolayer MoSe2 due to the same symmetry at the surface. However, the contribution from the surface field induced photocurrent is ~94.2% in bulk MoSe2 and it goes down to 74.5% in monolayer MoSe2. This is due to the larger surface depletion field in bulk MoSe2 (~2.54 × 107 V/m) compared with that in monolayer MoSe2 (~5.42 × 105 V/m). As such THz emission from bulk is approximately four times larger than that from monolayer MoSe2. This work not only proves clear THz radiation mechanism from MoSe2 crystals but also affords a THz technology for the surface characterization of two-dimensional materials.Funding Information
- the national key Research and Development Program of China (2019YFC1520904)
This publication has 48 references indexed in Scilit:
- Terahertz emission from semi-insulating GaAs with octadecanthiol-passivated surfaceApplied Surface Science, 2013
- Photoluminescence emission and Raman response of monolayer MoS_2, MoSe_2, and WSe_2Optics Express, 2013
- Band Bending in Semiconductors: Chemical and Physical Consequences at Surfaces and InterfacesChemical Reviews, 2012
- Layer-by-layer analysis of the linear optical response of clean and hydrogenated Si(100) surfacesPhysical Review B, 2006
- Optical rectification and shift currents in GaAs and GaP response: Below and above the band gapPhysical Review B, 2006
- Terahertz time-domain spectroscopy: A new tool for the study of glasses in the far infraredJournal of Non-Crystalline Solids, 2005
- Rectification and shift currents in GaAsApplied Physics Letters, 2002
- PEO intercalation in layered chalcogenidesAdvanced Materials, 1993
- Friction properties of sputtered dichalcogenide layersTribology International, 1981
- Mobility of Charge Carriers in Semiconducting Layer StructuresPhysical Review B, 1967