A Novel Synthesis Pathway Towards Rare Earth Fluorides by Using Liquid and Solid State Hexafluorophosphate Salts
Open Access
- 1 March 2021
- journal article
- research article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 168 (3), 036502
- https://doi.org/10.1149/1945-7111/abe8bc
Abstract
This work concerns different methods to synthesize rare earth fluorides by using liquid and solid state hexafluorophosphates. Various [PF6]− sources were compared, i.e. [BMIM][PF6], [TBA][PF6] and KPF6. Furthermore, the required reaction times and temperatures have been determined by XRD measurements. It turned out that [TBA][PF6] reacts even in the solid state at moderate temperatures to yield single phase LaF3. The use of hydroxides and oxides instead of the commonly employed nitrates as rare earth educts was successfully attempted. The reaction with rare earth hydroxide showed some peculiarities which were traced back to the specific reaction between HF and OH−. The reaction between [TBA][PF6] and La(OH)3 was studied in detail via the determination of oxygen and nitrogen concentrations as well as solid-state 19F and 139La nuclear magnetic resonance (NMR).Keywords
This publication has 35 references indexed in Scilit:
- Characterization and extinction measurement of potassium terbium fluoride single crystal for high laser power applicationsOptics Letters, 2017
- Out of the blue: semiconductor laser pumped visible rare‐earth doped lasersLaser & Photonics Reviews, 2016
- Efficient continuous wave laser operation of Tb3+‐doped fluoride crystals in the green and yellow spectral regionsLaser & Photonics Reviews, 2016
- Review of Faraday Isolators for Kilowatt Average Power LasersIEEE Journal of Quantum Electronics, 2014
- Ab initiostrategy for muon site assignment in wide band gap fluoridesPhysical Review B, 2013
- Nanopartikel für die AufwärtskonversionAngewandte Chemie, 2011
- Optical Transitions and Internal Vibronic Frequencies of MnF 6 2 - Ions in Cs2SiF6 and Cs2GeF6 Red PhosphorsJournal of the Electrochemical Society, 2011
- Luminescence properties of YPO4:Nd3+: a promising VUV scintillator materialNuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 2002
- UV and VUV optical excitations in wide band gap materials doped with rare earth ions: 4f–5d transitionsJournal of Alloys and Compounds, 1997
- On the nonradiative and radiative decay rates and a modified exponential energy gap law for 4f–4f transitions in rare-earth ionsThe Journal of Chemical Physics, 1983