Contrasting Controls on the Diel Isotopic Variation of Hg0 at Two High Elevation Sites in the Western United States
- 1 September 2020
- journal article
- research article
- Published by American Chemical Society (ACS) in Environmental Science & Technology
- Vol. 54 (17), 10502-10513
- https://doi.org/10.1021/acs.est.0c01918
Abstract
The atmosphere is a significant global reservoir for mercury (Hg) and its isotopic characterization is important to understand sources, distribution, and deposition of Hg to the Earth's surface. To better understand Hg isotope variability in the remote background atmosphere, we collected continuous 12-h Hg-0 samples for 1 week from two high elevation sites, Camp Davis, Wyoming (valley), and Mount Bachelor, Oregon (mountaintop). The samples collected at Camp Davis displayed strong diel variation in delta Hg-202 values of Hg-0, but not in Delta Hg-199 or Delta Hg-200 values. We attribute this pattern to nightly atmospheric inversions trapping Hg in the valley and the subsequent nighttime uptake of Hg by vegetation, which depletes Hg from the atmosphere. At Mount Bachelor, the samples displayed diel variation in both delta Hg-202 and Delta Hg-199, but not Delta Hg-200. We attribute this pattern to differences in the vertical distribution of Hg in the atmosphere as Mount Bachelor received free tropospheric air masses on certain nights during the sampling period. Near the end of the sampling period at Mount Bachelor, the observed diel pattern dissipated due to the influence of a nearby forest fire. The processes governing the Hg isotopic fractionation differ across sites depending on mixing, topography, and vegetation cover.This publication has 79 references indexed in Scilit:
- Changes in the mercury isotopic composition of sediments from a remote alpine lake in Wyoming, USAScience of The Total Environment, 2019
- A review of global environmental mercury processes in response to human and natural perturbations: Changes of emissions, climate, and land useAMBIO, 2018
- Isotopic Composition of Gaseous Elemental Mercury in the Free Troposphere of the Pic du Midi Observatory, FranceEnvironmental Science & Technology, 2016
- Uncertainties in Atmospheric Mercury Modeling for Policy EvaluationCurrent Pollution Reports, 2016
- Coupling atmospheric mercury isotope ratios and meteorology to identify sources of mercury impacting a coastal urban‐industrial region near Pensacola, Florida, USAGlobal Biogeochemical Cycles, 2015
- Comparison of mercury concentrations measured at several sites in the Southern HemisphereAtmospheric Chemistry and Physics, 2015
- A review of the sources of uncertainties in atmospheric mercury modeling II. Mercury surface and heterogeneous chemistry – A missing linkAtmospheric Environment, 2012
- Atmospheric mercury—An overviewAtmospheric Environment, 1998
- Atmospheric Mercury Speciation: Concentrations and Behavior of Reactive Gaseous Mercury in Ambient AirEnvironmental Science & Technology, 1998
- The biogeochemical cycling of elemental mercury: Anthropogenic influencesGeochimica et Cosmochimica Acta, 1994