Facile Synthesis of Proton-Type ZSM-5 by Using Quasi-Solid-Phase (QSP) Method

Abstract

Herein, a simple and green quasi-solid-phase (QSP) method for facile synthesis of proton-type ZSM-5 avoiding use of excessive water, dry gel, Na(+)cation and fluoride is reported. Crystallization by using the stoichiometric amount of TPAOH (tetrapropylammonium hydroxide) at 180 degrees C for only 12 h gave well-structured HZSM-5 crystals with high specific surface area of 429 m(2) g(-1)and high thermal stability. 5MRs was observed to closely relate the formation of MFI structure and QSP method exhibits shorter induction period (t(0)), higher nucleation rate (V-n), and faster growth rate (V-g). Moreover, HZ-12-180 showed extremely better and rather stable catalytic activity for methanol-to-propylene reaction by comparison with commercial HZSM-5.