Angewandte Chemie

Journal Information
ISSN / EISSN : 00448249 / 15213757
Current Publisher: Wiley (10.1002)
Total articles ≅ 58,322
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Latest articles in this journal

Chen Tan, Michelle Lee, Mohammad Arshadi, Morteza Azizi, Alireza Abbaspourrad
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.201916211

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Min Zhou, Yuxin Qian, Jiayang Xie, Wenjing Zhang, Weinan Jiang, Ximian Xiao, Sheng Chen, Chengzhi Dai, Zihao Cong, Zhemin Ji, et al.
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.202000505

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Yueyu Tong, Haipeng Guo, Daolan Liu, Xiao Yan, Ji Liang, Panpan Su, Si Zhou, Jian Liu, Gao Qing (Max) Lu, Shi Xue Dou
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.202002029

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Long Chen, Changlong Chen, Yue Sun, Shuai Lu, Haohui Huo, Tianyi Tan, Anquan Li, Xiaopeng Li, Goran Ungar, Feng Liu, et al.
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.201915055

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Guangbin Dong, Si-Hua Hou, Adriana Y. Prichina, Mengxi Zhang
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.201915821

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Guozhi Xiao, Yunqin Zhang, Zixi Chen, Yingying Huang, Shaojun He, Xingkuan Yang, Zhibing Wu, Xiufang Wang
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.202000992

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Yang Jiao, Lei Zhang, Xu Gao, Wen Si, Chunying Duan
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.201915040

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Zhen Yang, Mieke Möller, Rene M. Koenigs
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.201915500

Abstract:A palladium catalyzed C‐H functionalization and consecutive β‐fluoride elimination reaction between indole heterocycles and fluorinated diazoalkanes is reported. This approach provides a facile method for the rapid synthesis of gem‐difluoro olefins using fluorinated diazoalkanes under mild reaction conditions, which is, to the best of our knowledge, reported for the first time in this work. Cyclopropanation products were obtained, when N‐arylated rather than N‐alkylated indoles were applied in this reaction. Mechanistic studies reveal the importance of the β‐fluoride elimination step in this transformation. This methodology presents a new concept for a simple and direct transfer of a 1‐aryl‐(2,2‐difluorovinyl) group to access gem‐difluoro olefins.
Rodolphe Clerac, Jun-Liang Liu, Kasper Steen Pedersen, Samuel M. Greer, Itziar Oyarzabal, Abhishake Mondal, Stephen Hill, Fabrice Wilhelm, Andrei Rogalev, Alain Tressaud, et al.
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.201914934

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Robert N. Grass, Reinhard Heckel, Christophe Dessimoz, Wendelin J. Stark
Published: 21 February 2020
by Wiley
Angewandte Chemie; doi:10.1002/ange.202001162

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