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(searched for: doi:10.5155/eurjchem.8.1.15-17.1521)
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European Journal of Chemistry, Volume 11, pp 50-59; doi:10.5155/eurjchem.11.1.50-59.1945

Abstract:
A series of imidazole derivatives (1-3) were synthesized with three component reaction among benzil, ammonium acetate and formaldehyde/aromatic aldehyde at 110 °C without a catalyst and solvent. These synthesized imidazole derivatives have shown intermolecular hydrogen bonding such as N-H···N and O-H···N. The imidazole 1 and 2 exhibited N-H···N intermolecular hydrogen bonding while imidazole 3 exhibited O-H···N intermolecular hydrogen bonding. The hydrogen bonds in imidazoles were studied by X-ray crystallography and Hirshfeld Surface Analysis at dnorm surface which show the visible red spots, indicated for hydrogen bonds. Further, Hirshfeld surface analysis also shows the percentage of all intermolecular interactions.
Ikram Saadaoui, Fatma Krichen, , Riadh Ben Mansour, Nabil Miled, Ali Bougatef, Mohamed Kossentini
Published: 1 March 2019
Journal of Molecular Structure, Volume 1180, pp 344-354; doi:10.1016/j.molstruc.2018.12.008

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Manish Kumar Dixit,
Physical Chemistry Chemical Physics, Volume 20, pp 23762-23772; doi:10.1039/c8cp04579h

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