In this article, modification of the residual power series method (RPSM) is proposed for higher order boundary value problems (BVPs). The proposed algorithm is tested against various linear and nonlinear BVPs of orders nine up to thirteen. For the efficiency check of RPSM, obtained series solutions are compared with other available results in the literature. Analysis indicates that RPSM is better in terms of accuracy as compared to other mentioned schemes. As RPSM is applicable to BVPs without linearization, discretization, and perturbation, hence practically it is the best suitable solution tool for more complex BVPs in science and engineering.