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(searched for: (10.5155/eurjchem.10.1.72-81.1812))
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Sciprofile linkGanesan Nalini, Natesan Jayachandramani, Sciprofile linkRadhakrishnan Suresh, Prakasam Thirumurugan, Venugopal Thanikachalam, Govindasamy Manikandan, Sciprofile linkDharmalingam Sankari
European Journal of Chemistry, Volume 10, pp 72-81; doi:10.5155/eurjchem.10.1.72-81.1812

Abstract:
A new compound, spiro-oxindole derivative compound namely ethyl-2ʹ-amino-5ʹ-cyano-6ʹ-(1H-indole-3yl)-2-oxospiro[indoline-3,4ʹ-pyran]-3ʹ-carboxylate (EACIOIPC) has been synthesized and characterized by microanalysis, FT-IR, mass spectrum and NMR (1H and 13C) techniques. The thermal decomposition of the compound was studied by thermogravimetric analysis under dynamic nitrogen atmosphere at different heating rates of 10, 15, 20 and 30 K/min. The kinetic parameters were calculated using model-free (Friedman’s, Kissinger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO) methods) and model-fitting (Coats and Redfern (CR)) methods. The decomposition process of EACIOIPC followed a single step mechanism as evidenced from the data. Existence of compensation effect is noticed for the decomposition of EACIOIPC. Invariant kinetic parameters are consistent with the average values obtained by Friedman and KAS in conversional methods.
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