Mechanistic insights into Ni-catalyzed hydrogen atom transfer (HAT)-triggered hydrodefluorination of CF3-substituted alkenes
- 8 June 2021
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 50 (26), 9026-9030
- https://doi.org/10.1039/d1dt01799c
Abstract
We report the first computational study on a nickel hydride HAT-initiated catalytic reaction, a novel hydrodefluorination of CF3-substituted aryl alkenes to afford gem-difluoroalkenes.Keywords
Funding Information
- Shenzhen Polytechnic
- University of Colorado Denver
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