Activated Carbon Based on Acacia Wood (Auriculeaformis, Côte d’Ivoire) and Application to the Environment through the Elimination of Pb2+ Ions in Industrial Effluents

Abstract

The objective of this study is to develop carbon, that of Acacia auriculeaformis through its activation in order to eliminate lead in an aqueous medium. A series of activated carbon has been prepared by chemical activation with phosphoric acid, sodium hydroxide and sodium chloride. The determination of the physico-chemical properties of the prepared carbon guided the choice of phosphoric acid activated carbon as the best adsorbent for the elimination of lead(II) in an aqueous solution. Pb2+ adsorption tests in batch mode have shown that the adsorption capacity is influenced by various parameters such as mass, pH, concentration of Pb2+ ions and contact time linked to the medium and the adsorbent. Adsorption isotherms, kinetic models and thermodynamics have been used to describe the adsorption process. The equilibrium data for activated charcoal correspond well to the model of Freundlich, Langmuir, Temkin and Kiselev. The kinetic adsorption data proved to be better described by the pseudo-second order model with external and intraparticle diffusion which are two decisive steps in the adsorption process of Pb2+ ions. Thermodynamics and adsorption isotherms predict a spontaneous exothermic surface reaction, of the chemisorption type, with ion retention in orderly monolayers on the heterogeneous surface of the adsorbent. Tests carried out with this adsorbent material have contributed to the elimination of the Pb2+ ions contained in an industrial effluent with a reduction rate reaching 42.52% against 85.90% in a synthetic solution.