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Interpretation of Adsorption Thermodynamics and Kinetics

Augustus Newton Ebelegi, Nimibofa Ayawei, Donbebe Wankasi
Open Journal of Physical Chemistry , Volume 10, pp 166-182; doi:10.4236/ojpc.2020.103010

Abstract: A complete study of adsorption processes will be less complete if the structure and dynamics of its different elements and how they interact is not well captured. Therefore, the extensive study of adsorption thermodynamics in conjunction with adsorption kinetics is inevitable. Measurable thermodynamic properties such as temperature equilibrium constant and their non-measurable counterparts such as Gibbs free energy change, enthalpy, entropy etc. are very important design variables usually deployed for the evaluation and prediction of the mechanism of adsorption processes.
Keywords: Activation energy / Gibbs free energy / STICKING PROBABILITY / entropy change / Elovich Model / Adsorption Density / Pseudo-second-order Kinetic Model / Brouers-Sotolongo Fractal Kinetic Model

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