HYDROGENATION OF CARBON DIOXIDE ON SIRAL ALUMINOSILICATES MODIFIED WITH COBALT AND PALLADIUM
Open Access
- 30 May 2022
- journal article
- Published by Azerbaijan State Oil and Industry University in Azerbaijan Journal of Chemical News
- Vol. 04 (01), 81-86
- https://doi.org/10.32010/ajcn05012022-81
Abstract
The reaction of hydrogenation of CO2 in flow mode at atmospheric pressure on Siral aluminosilicates with 1, 10, and 40 wt.% SiO2 and containing Co and Co-Pd has been studied. The synthesized catalysts were characterized by XRD and EPR spectroscopy. It has been established that on catalysts containing only cobalt, at a reaction temperature of ≤ 300oC, practically only methane is formed, and at a reaction temperature of T ≥ 300oC, methane and no more than 1% CO are formed. It is shown that with an increase in the SiO2/Al2O3 ratio, a decrease in the methane yield is observed. The introduction of palladium into the composition of the Co/Siral catalyst stimulates the formation of methanol, the yield of which increases with an increase in the reaction temperature and reaches its maximum value at a reaction temperature of 500°C for the Co,Pd/Siral-10 catalyst. The mechanism of the reaction of CO2 hydrogenation to methanol and the role of palladium in this reaction are discussed. Keywords: carbon dioxide, hydrogenation, methane, methanol, Siral, Pd, Co.Keywords
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