SYNTHESIS OF SILVER- AND GOLD-N-HETEROCYCLIC CARBENE COMPLEXES INCLUDING STRONG METAL-CARBON BINDING
- 5 January 2022
- journal article
- Published by Hacettepe University in Hacettepe Journal of Biology and Chemistry
- Vol. 50 (1), 31-36
- https://doi.org/10.15671/hjbc.817435
Abstract
In this study, the new benzimidazolium salt (1) containing ether functionalized alkyl group as the NHC ligand precursor was synthesized. Ag-NHC complex (2) was synthesized by interaction with Ag2O of this ligand precursor. The Au-NHC complex was synthesized by interaction the [AuCl(PPh3)] complex with the synthesized Ag-NHC complex. The structures of prepared all new compounds were characterized by different spectroscopic methods. Bu çalışmada, NHC ligand öncüsü olarak eter fonksiyonlu alkil grubu içeren yeni benzimidazol tuzu (1) sentezlendi. Ag-NHC kompleksi (2) bu ligand öncüsünün Ag2O ile etkileştirilmesiyle sentezlendi. Au-NHC kompleksi (3) sentezlenmiş Ag-NHC kompleksi ile [AuCl(PPh3)] kompleksinin etkileştirilmesiyle sentezlendi. Hazırlanan tüm yeni bileşiklerin yapısı farklı spektroskopik metotlar ile karakterize edildi.Keywords
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