Dielectric, magnetic and magneto-dielectric properties of (La, Co) co-doped BiFeO3
- 20 September 2019
- journal article
- research article
- Published by IOP Publishing in Physica Scripta
- Vol. 94 (12), 125805
- https://doi.org/10.1088/1402-4896/ab354a
Abstract
BLFCO [Bi1-xLaxFe1-xCoxO3(x = 0.00, 0.01, 0.03, 0.05, 0.10)] ceramics were synthesized using sol-gel technique. The effect of Lanthanum (La) and Cobalt (Co) co-doping in BiFeO3 (BFO) on structural, electrical, magnetic and magneto-dielectric (MD) properties are systematically investigated. The phase purity and crystal structures were studied using x-ray diffraction technique. The dielectric properties [dielectric constant (epsilon) and tangent loss (tan delta)] were studied as a function of frequency and temperature for pure and co-doped BFO samples. The magnetization study reveals that the ferromagnetic (FM) properties in La and Co co-doped samples enhance with an increasing dopant concentration. The coercive field is found to increase with the doping concentration suggest a competition between the antiferromagnetic and FM ordering. The zero-field-cooled (ZFC) and field-cooled (FC) magnetization measurements of these samples also confirm the change in the magnetic behaviour of BLFCO as doping concentration increases. ZFC and FC magnetization curves split at low temperature with sharp cusps suggest a spin-glass like behaviour of BLFCO. The pure and co-doped samples exhibit a MD coupling effect. Furthermore, the anomaly near the magnetic phase transition (around the Neel temperature of BFO) implies the MD coupling in BLFCO samples.Keywords
Funding Information
- University Grants Commission (F.30-461/2019(BSR))
This publication has 85 references indexed in Scilit:
- Dispersion studies of La substitution on dielectric and ferroelectric properties of multiferroic BiFeO3 ceramicCeramics International, 2012
- Electric control of magnon frequencies and magnetic moment of bismuth ferrite thin films at room temperatureApplied Physics Letters, 2011
- Dielectric, magnetic, and magnetoelectric properties of La and Ti codoped BiFeO3Applied Physics Letters, 2010
- Size effect on magnetic and ferroelectric properties in Bi2Fe4O9 multiferroic ceramicsJournal of Applied Physics, 2009
- Physics and Applications of Bismuth FerriteAdvanced Materials, 2009
- Synthesis and weak ferromagnetism of Dy-doped BiFeO3 powdersMaterials Letters, 2009
- Enhanced electrical properties in multiferroic BiFeO3ceramics co-doped by La3+and V5+Journal of Physics D: Applied Physics, 2008
- Ferroelectric, electrical and magnetic properties of Cr, Mn, Co, Ni, Cu added polycrystalline BiFeO3 filmsApplied Physics Letters, 2008
- Magnetic control of ferroelectric polarizationNature, 2003
- Epitaxial BiFeO 3 Multiferroic Thin Film HeterostructuresScience, 2003