Synthesis and Dissociation Behavior of Degradable Network Polymers Consisting of Epoxides and 9-Anthracene Carboxylic Acid Dimer
- 1 October 2021
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 50 (10), 1787-1790
- https://doi.org/10.1246/cl.210332
Abstract
Photodimer of 9-anthracene carboxylic acid was used as crosslinker for bisepoxides and a degradable network polymer was synthesized at 100–110 °C in the presence of a base catalyst. The resulting network polymer was thermally decrosslinked at 150 °C within 30 min and completely solubilized in an organic solvent. Detailed investigation of the thermal dissociation behavior revealed that dissociation of more than 80% of 9-AC dimer unit was required for complete solubilization of the network polymer.Keywords
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