The potential of biodegradable polymers has long been appreciated. In this work, an attempt has been made to synthesize biodegradable polymer composite from potato starch and low density polyethylene (LDPE) with different ratios of starch (0%-15% w/w) by using an extruder. The structure and morphology of film surfaces was studied using X-ray diffraction and scanning electron microscopy (SEM) respectively. The physical (density, water absorption), mechanical (tensile, flexural) and thermal (TGA and DTA) analyses of starch/LDPE bio-composites were evaluated through standard methods and instruments. Biodegradation tendency was investigated utilizing soil burial and Rockwell micro-hardness test.The results revealed that the density and water absorption of polymer blends increased with increasing the starch content in starch/LDPE composites. The tensile strength and elongation at break decreased with starch content whereas the elastic modulus, flexural strength and flexural modulus rose. The biodegradability of composites enhanced by increasing the starch content and the result was backed by weight loss during burial of the samples in soil for 90 days. Microhardness test also supported the biodegradation probability as hardness found to reduce extensively after soil burial. However, further study to decide the optimum starch loading alongwith some modifications to starch and LDPE is highly suggested to have a biodegradable LDPE polymer composite in a realistic time frame.