Thermal Cycling of a MOF-Based NO Disproportionation Catalyst
- 6 January 2021
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 143 (2), 681-686
- https://doi.org/10.1021/jacs.0c12134
Abstract
The metal–organic framework CuI-MFU-4l reacts with NO, initially forming a copper(I)-nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII–NO2 and N2O. The thermal stability of MFU-4l allows NOx to be released from the framework at temperatures greater than 200 °C. This treatment regenerates the original CuI-MFU-4l, which can engage in subsequent cycles of NO disproportionation.Funding Information
- Ford Motor Company
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