Thermodynamic Analysis and Experimental Investigation of Al and F Removal from Sulfuric Acid Leachate of Spent LiFePO4 Battery Powder
Open Access
- 15 October 2021
- Vol. 11 (10), 1641
- https://doi.org/10.3390/met11101641
Abstract
The co-precipitation thermodynamics of the Li+–Fe2+/Fe3+–Al3+–F−–SO42−–PO43−–H2O system at 298 K is studied, aiming to understand the precipitation characteristics. Based on the principle of simultaneous equilibrium and the mass action law, the missing Ksp values of AlF3 and FeF3 were estimated. The results of thermodynamic calculation demonstrate that Al3+ and F− in the sulfuric acid leachate could be preferentially precipitated in the form of AlPO4 and FeF3 by the precise adjustment of the final pH value. Only a small amount of P and Fe was lost by the precipitation of Fe3(PO4)2·8H2O, FePO4, and Fe(OH)3 during the purification process. Controlling the oxidation of ferrous ions effectively is of critical significance for the loss reduction of P and Fe. Precipitation experiments at different pH value indicated that the concentration of Al3+ and F− in the leachate decreased as the final pH value rose from 3.05 to 3.90. When the final pH value was around 3.75, aluminum and fluoride ion impurities could be deeply purified, and the loss rate of phosphate ions and iron ions could be reduced as much as possible. Relevant research results can provide theoretical guidance for the purification of leachate in the wet recycling process of lithium-ion batteries.Keywords
Funding Information
- Hunan Provincial Key Research and Development Projects (2019SK2061, GK-201806)
This publication has 37 references indexed in Scilit:
- Cobalt products from real waste fractions of end of life lithium ion batteriesWaste Management, 2016
- A novel process to recycle spent LiFePO4 for synthesizing LiFePO4/C hierarchical microflowersElectrochimica Acta, 2016
- Selective extraction and separation of nickel from cobalt, manganese and lithium in pre-treated leach liquors of ternary cathode material of spent lithium-ion batteries using synergism caused by Versatic 10 acid and LIX 84-IHydrometallurgy, 2016
- A green recycling process designed for LiFePO4 cathode materials for Li-ion batteriesJournal of Materials Chemistry A, 2015
- Process Development for the Recycle of Spent Lithium Ion Batteries by Chemical PrecipitationIndustrial & Engineering Chemistry Research, 2014
- Synthesis and performance of Li[(Ni1/3Co1/3Mn1/3)1−xMgx]O2 prepared from spent lithium ion batteriesJournal of Hazardous Materials, 2013
- The Spin-Polarized Electronic Structure of LiFePO4 and FePO4 Evidenced by in-Lab XPSThe Journal of Physical Chemistry C, 2010
- Recovery of cobalt sulfate from spent lithium ion batteries by reductive leaching and solvent extraction with Cyanex 272Hydrometallurgy, 2010
- Reaction mechanism and electrochemical performance of LiFePO4/C cathode materials synthesized by carbothermal methodElectrochimica Acta, 2009
- Precipitation of phosphate from solution using aluminum saltWater Research, 1975