Synthesis of Fe3O4@MIL-100(Fe) nanocatalyst and comparative evaluation of photocatalytic behavior of Fe3O4 and core-shell structure of catalyst on methylene blue degradation
- 18 October 2021
- journal article
- research article
- Published by Taylor & Francis Ltd in Molecular Crystals and Liquid Crystals
- Vol. 736 (1), 103-112
- https://doi.org/10.1080/15421406.2021.1992086
Abstract
In this study, the first magnetite nanoparticles (Fe3O4), and MIL-100(Fe) nanocatalyst via in situ two-step hydrothermal strategies were synthesized in which Fe3O4 is known as the magnetic core. MIL-100 (Fe) grows as a shell at the Fe3O4 level and adjusts the shell thickness by precisely controlling the reaction time from 37.10 to 45.95 nm. The structural, morphological, magnetically, optical, and chemical bonding studies; XRD, FESEM, TEM, VSM, UV-Vis, and FTIR measurements were carried out. The results of the above analyses demonstrated core-shell structure is formed. The catalyst synthesized in the degradation of methylene blue was investigated as a heavy organic compound.Keywords
This publication has 22 references indexed in Scilit:
- The removal of bisphenol A from aqueous solutions by MIL-53(Al) and mesostructured MIL-53(Al)Journal of Colloid and Interface Science, 2013
- An expedient four-component domino protocol for the synthesis of novel benzo[a]phenazine annulated heterocycles and their photophysical studiesGreen Chemistry, 2012
- Extracting organic contaminants from water using the metal–organic framework CrIII(OH)·{O2C–C6H4–CO2}Physical Chemistry Chemical Physics, 2011
- Silica-bonded S-sulfonic acid: an efficient and recyclable solid acid catalyst for the synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols)Tetrahedron Letters, 2010
- Microwave Synthesis of Chromium Terephthalate MIL‐101 and Its Benzene Sorption AbilityAdvanced Materials, 2006
- Separation of Hydrocarbons with a Microporous Metal–Organic FrameworkAngewandte Chemie, 2006
- Separation of Hydrocarbons with a Microporous Metal–Organic FrameworkAngewandte Chemie, 2006
- Silica Sulfuric Acid as a Mild and Efficient Reagent for the Acetylation of Alcohols in Solution and under Solvent Free ConditionsBulletin of the Korean Chemical Society, 2004
- Preparation of Some New Benzylidenemalononitriles by an SNAr Reaction: Application to Naphtho[1,2-b]pyran SynthesisHETEROCYCLES, 1994
- Synthesis of 1,4-Dihydropyridines by Cyclocondensation ReactionsHETEROCYCLES, 1988