Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
Open Access
- 1 January 2013
- journal article
- research article
- Published by Hindawi Limited in Journal of Chemistry
- Vol. 2013, 1-9
- https://doi.org/10.1155/2013/536562
Abstract
New benzoyl thiourea derivatives and their nickel and copper complexes were synthesized. The structure of the synthesized compounds were confirmed by elemental analysis, FT-IR, and1H NMR techniques. Four of the synthesized compounds are analyzed by X-ray single crystal diffraction technique. WhereasN,N-dimethyl-N′-(4-fluorobenzoyl)thiourea,N,N-diethyl-N′-(4-fluorobenzoyl)thiourea, andN,N-di-n-butyl-N′-(4-fluorobenzoyl) thiourea crystallize in the monoclinic system,bis(N,N-di-n-propyl-N′-(4-fluorobenzoyl)thioureato) nickel(II) complex crystallizes in the triclinic system. These ligand molecules form dimers through strong intermolecular hydrogen bonds such as N–H⋯S, C–H⋯O, and N–H⋯O. Moreover, there are different types of intramolecular interactions in the crystal structures.Bis(N,N-dimethyl-N′-(4-fluorobenzoyl)thioureato) nickel(II) complex has a nearly square-planar coordination. The distance of nickel atom from the best plane through the coordination sphere is 0.029 Å.Keywords
Funding Information
- Mersin University Research (BAP-FBE KB (GB) 2006-1 DR)
This publication has 35 references indexed in Scilit:
- Synthesis, characterization and antibacterial activity of nickel (II) and copper (II) complexes of N-(alkyl(aryl)carbamothioyl)-4-nitrobenzamideEuropean Journal of Chemistry, 2010
- FT-IR, FT-Raman and ab-initio studies of 1,3-diphenyl thioureaEuropean Journal of Chemistry, 2010
- Theoretical and experimental studies on N-(6-methylpyridin-2-yl-carbamothioyl)biphenyl-4-carboxamideEuropean Journal of Chemistry, 2010
- Synthesis and Characterization ofN-(2,2-Diphenylacetyl)-N′-Substituted Thiourea Derivatives: The Crystal Structure ofN-(2,2-Diphenylacetyl)-N′-(4-chloro phenyl)-thioureaPhosphorus, Sulfur, and Silicon and the Related Elements, 2009
- Synthesis, characterization, and antimicrobial activity of new benzoylthiourea ligandsChemical Papers, 2009
- The crystal structure of 1-(4-chlorophenyl)-3-(4-methylbenzoyl)thioureaOpen Chemistry, 2005
- Synthesis, Characterization And Antitumor Activity Of Copper(II) Complexes, [CuL2] [HL1-3=N,N-Diethyl-N'-(R-Benzoyl)Thiourea (R=H, o-Cl and p-NO2)]Bioinorganic Chemistry and Applications, 2005
- Synthesis and insecticidal activity of new substituted N-aryl-N′-benzoylthiourea compoundsJournal of Fluorine Chemistry, 2003
- Chiral and achiral platinum(II) complexes for potential use as chemotherapeutic agents: crystal and molecular structures of cis-[Pt(L1)2] and [Pt(L1)Cl(MPSO)] [HL1 = N,N-diethyl-N ′-benzoylthiourea]J. Chem. Soc., Dalton Trans., 2000
- Thermal behaviours of Co(II), Ni(II), Cu(II)), and Pb(II) complexes of N,N-dipropyl-N′-benzoylthioureaThermochimica Acta, 1999