In situ synthesis of zeolites by geopolymerization with NaOH/KOH mixed solution and their potential application for Cd(II) immobilization in paddy soil

Abstract

Geopolymers can be transformed into zeolites under certain synthesis conditions. However, zeolite formation is not frequently reported in KOH-activated geopolymers. This study attempted to explore zeolite synthesis through geopolymerization for a curing time of 24 h using mixed NaOH/KOH alkaline solution as an activator, and then applying the geopolymer-supported zeolites to immobilize Cd(II) in paddy soil. The K2O/M2O-H2O/SiO2 and K2O/M2O-OH-/SiO2 binary zeolite crystallization phase diagrams were obtained. Zeolite A, faujasite and sodalite formed at lower K2O/M2O molar ratios (0-0.2), ferrierite formation was favoured at a K2O/M2O molar ratio of 0.2-0.4 and zeolite K-I and zeolite F-K (both K-zeolites) were observed at a K2O/M2O molar ratio of 0.6. The geopolymer-supported zeolites had micropores and mesopores and specific surface area values of 44.2-74.8 m(2) g(-1). The material displayed a considerable Cd(II) immobilization efficiency (55.6-58.7% at 4-6 wt.% addition of zeolite).