Ni‐Catalyzed Regioselective Hydroarylation of 1‐Aryl‐1,3‐Butadienes with Aryl Halides
- 10 September 2021
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 27 (64), 15903-15907
- https://doi.org/10.1002/chem.202102847
Abstract
An efficient nickel-catalyzed regioselective hydroarylation of 1,3-dienes with aryl halides and a silane has been developed, affording a range of allylic arenes in good to excellent yields under mild conditions. This method exhibits broad substrate scope, and excellent functional group tolerance. Late-stage modification of complex architectures was demonstrated.Funding Information
- National Natural Science Foundation of China (21790333, 21772221)
- Chinese Academy of Sciences (QYZDY-SSW-SLH012)
This publication has 60 references indexed in Scilit:
- Sulfoximines: A Neglected Opportunity in Medicinal ChemistryAngewandte Chemie, 2013
- Sulfoximine: Eine vernachlässigte Chance in der medizinischen ChemieAngewandte Chemie, 2013
- N‐Heterocyclic Carbene Complexes of Nickel as Efficient Catalysts for Hydrosilylation of Carbonyl DerivativesAdvanced Synthesis & Catalysis, 2012
- Asymmetric palladium-catalyzed hydroarylation of styrenes and dienesTetrahedron, 2011
- Palladium-Catalyzed Hydroarylation of 1,3-Dienes with Boronic Esters via Reductive Formation of π-Allyl Palladium Intermediates under Oxidative ConditionsJournal of the American Chemical Society, 2010
- Nickel-Catalyzed Alkenylation and Alkylation of Fluoroarenes via Activation of C−H Bond over C−F BondJournal of the American Chemical Society, 2008
- Gold(I)‐Catalyzed Intermolecular Hydroarylation of Alkenes with Indoles under Thermal and Microwave‐Assisted ConditionsChemistry – A European Journal, 2008
- Nickel-catalysed addition of organoboronates to 1,3-dienesElectronic supplementary information (ESI) available: 1H NMR spectra and MS data. See http://www.rsc.org/suppdata/cc/b2/b207185a/Chemical Communications, 2002
- Chemistry of tetrakis(triethyl phosphite)nickel hydride, HNi[P(OEt)3]4+. IV. Mechanism of olefin isomerizationJournal of the American Chemical Society, 1972
- The Mechanism of Isomerization of Olefins with Transition Metal CatalystsJournal of the American Chemical Society, 1966