Electronic modulation of novel W18O49 nanoshuttles for efficient hydrogen evolution reaction
- 30 July 2020
- journal article
- research article
- Published by IOP Publishing in Nanotechnology
- Vol. 31 (42), 425705
- https://doi.org/10.1088/1361-6528/ab9fb5
Abstract
Research on transition metal oxides for hydrogen evolution reaction (HER) is challenging due to their poor electrical conductivity and weak hydrogen adsorption. In this paper, a class of W18O49 nanoshuttles (NSs) with highly bifurcated structure at both ends were synthesized via a hydrothermal method for highly efficient HER. By simply introducing Nb and Pt components, W18O49 can achieve optimal hydrogen adsorption through electronic modulation. The optimized NbPt/W18O49 NSs show an extremely low overpotential of 37 mV to obtain 10 mA cm-2 and an unprecedented small Tafel slope of 23 mV dec-1, superior to commercial Pt/C. The NbPt/W18O49 NSs can endure long-term stability for 18 h with negligible morphology change and performance degradation. Based on the surface valence band spectra of x-ray photoelectron spectroscopy and density functional theory calculations, the improved HER activity is closely related to the optimization of hydrogen binding energy on active sites and activation of inert O sites of W18O49. This study opens a facile avenue of electronic modulation to promote electrocatalytic performance.Keywords
Funding Information
- Zhejiang Provincial Natural Science Foundation of China (LQ18E030010)
This publication has 40 references indexed in Scilit:
- Mo Doping Induced More Active Sites in Urchin‐Like W18O49 Nanostructure with Remarkably Enhanced Performance for Hydrogen Evolution ReactionAdvanced Functional Materials, 2016
- 2D Transition‐Metal‐Dichalcogenide‐Nanosheet‐Based Composites for Photocatalytic and Electrocatalytic Hydrogen Evolution ReactionsAdvanced Materials, 2015
- A Review of Phosphide‐Based Materials for Electrocatalytic Hydrogen EvolutionAdvanced Energy Materials, 2015
- Local atomic structure modulations activate metal oxide as electrocatalyst for hydrogen evolution in acidic waterNature Communications, 2015
- Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticlesNature Communications, 2014
- Ultrathin W18O49 Nanowire Assemblies for Electrochromic DevicesNano Letters, 2013
- Opportunities and challenges for a sustainable energy futureNature, 2012
- Electrocatalyst approaches and challenges for automotive fuel cellsNature, 2012
- Comparative Characterization of Fungal Anthracenone and Naphthacenedione Biosynthetic Pathways Reveals an α-Hydroxylation-Dependent Claisen-like Cyclization Catalyzed by a Dimanganese ThioesteraseJournal of the American Chemical Society, 2011
- Towards the computational design of solid catalystsNature Chemistry, 2009