Carboxymethyl Cellulose Hydrogel Based Formulations of Zinc Hydroxide Nitrate-Sodium Dodecylsulphate-Bispyribac Nanocomposite: Advancements in Controlled Release Formulation of Herbicide

Abstract

The usefulness of carboxymethyl cellulose (CMC) as a matrix material in enhancing the controlled release formulations of bispyribac (BP) herbicide from the interlayer gallery of zinc hydroxide nitratesodium dodecylsulphate–bispyribac (ZHN–SDS–BP) nanocomposite was investigated. The CMC coated nanocomposite, ZHN–SDS–BP–CMC was characterised using several instruments for the determination of its physicochemical properties. The release rates of the BP were measured using a UV spectrophotometer, and the aqueous solutions containing PO3− 4 , SO2− 4 and Cl− were selected as release media in the release studies so as to mimic the real conditions of environmental soil. Significant release time delays, triggered by the gelation forming ability and hygroscopic nature of CMC, were observed in all release media, and the release processes were found to behave in a concentration-dependent manner in all release media. Fitting the release data into several kinetic models demonstrated that release in aqueous solutions of Na3PO4 and Na2SO4 was governed by pseudo second order processes, whereas the release in an aqueous NaCl solution was governed by the parabolic diffusion kinetic model. The potential of CMC in prolonging the release of BP from ZHN–SDS–BP–CMC can potentially help in reducing the pollution resulting from the overuse of pesticides.