随着电子商务技术的不断发展与应用，物资的利用率却并未随之相应提高，因此带来的是大量价值的浪费与闲置。根据创建节约型社会的需要，如何有效提高物资的回收与流转尤为重要。而在传统的电子商务技术的物资回收流转中，如何解决因信息不对称带来的信任缺失问题非常困难。本文研究在小型区域的物资回收流转过程中如何通过区块链技术提高物资流转的多方信任程度从而提高物资回收流转概率和减少价值浪费，创新地使用零知识证明技术保证价值流转过程中地隐私。并且，本文在典型的小型特征区域进行基于区块链技术的高可信度物资回收流转系统的设计、实现与应用。结果表明，区块链技术在小型区域价值流转系统中构建了新的基于算法的信任机制体系，减少信息不对称带来的信任缺失问题，有效提高价值流转效率。 With the continuous development and application of e-commerce technology, the utilization rate of materials has not been correspondingly increased, so a large amount of value is wasted and idle. According to the needs of creating a conservation-minded society, how to effectively improve the recycling and circulation of materials is particularly important. However, in the material recycling and circulation of traditional e-commerce technology, it is very difficult to solve the problem of lack of trust caused by information asymmetry. This paper studies how to use blockchain technology to improve the multi-party trust of material circulation in the process of material recovery and circulation in small areas, thereby increasing the probability of material recovery and circulation and reducing value waste, innovatively use zero-knowledge proof technology to ensure wealth in the process of value transfer. In addition, this article designs, implements and applies a high-relia- bility material recovery and circulation system based on blockchain technology in a typical small characteristic area. The results show that blockchain technology builds a new algorithm-based trust mechanism system in a small regional value transfer system, reduces the lack of trust caused by information asymmetry, and effectively improves the efficiency of value transfer.