Ordered mesoporous carbon assisted Fe–N–C for efficient oxygen reduction catalysis in both acidic and alkaline media
- 3 January 2020
- journal article
- research article
- Published by IOP Publishing in Nanotechnology
- Vol. 31 (16), 165708
- https://doi.org/10.1088/1361-6528/ab674c
Abstract
Fe-N-C catalyst obtained by high temperature pyrolysis is one of the most promising electrocatalysts for non-precious metal oxygen reduction reaction (ORR). However, up to now, the lesser density of active sites results in a substantial performance gap between the Fe-N-C materials and the conventional Pt/C ORR catalysts. Herein, an N-doped mesoporous carbon is employed as the support for the dispersion of poly-m-phenylenediamine. With high specific surface areas of 1526 m2 g-1, the as-prepared Fe-N-C materials show the half-wave potential of 0.89 V and 0.79 V in 0.1 M KOH and 0.5 M H2SO4, respectively. Notably, the superior methanol tolerance, as well as excellent stability, makes our Fe-N-C materials as competitive candidates for oxygen electrochemical catalysis.Keywords
Funding Information
- China Postdoctoral Science Foundation (2019M652155)
- Key Program of the Chinese Academy of Sciences (KFZD-SW-320)
- Opened Fund of the State Key Laboratory on Integrated Optoelectronics (IOSKL2017KF08M)
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