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ChemInform Abstract: Direct Access to 2-Amino-5-azidomethylfurans Through Palladium-Catalyzed Azidative Cycloisomerization of Homoallenyl Amides.

Qianwen Huang, Hanliang Zheng, Shuiyou Liu, Lichun Kong, Fang Luo,
Published: 6 December 2016

Abstract: A novel azidative cycloisomerization of homoallenyl amides (I) and (III) using TmsN3 as the azidation reagent and a hypervalent iodine reagent as the oxidant giving a series of azidomethyl-furans (II) and (IV), resp., is presented.
Keywords: furan derivatives / ring closure reactions, annulation reactions

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