On the Galvanic Modification of Seawater
Open Access
- 1 January 2019
- journal article
- research article
- Published by Scientific Research Publishing, Inc. in World Journal of Condensed Matter Physics
- Vol. 09 (04), 112-121
- https://doi.org/10.4236/wjcmp.2019.94009
Abstract
Chemical properties of seawater are studied at forced shifting of Fermi level εF in the band gap of liquid water due to deviation of its composition H2O1−z ( | z|−13 ) from the stoichiometric one ( z = 0 ). It is shown that the hypo-stoichiometric state ( z > 0 ) of seawater emerges when Fermi level is shifted to the local electron level εH3O of hydroxonium H3O+ in galvanic cell with the strongly polarized anode and the quasi-equilibrium cathode. Then, each εH3O is occupied by electron and hydroxonium radicals [H3O] together with hydroxide anions [OH−] form in seawater hydrated electrons [(H2O)2−] . The opposite hyper-stoichiometric state ( z εOH for removing electron from each hydroxide ion OH− and forming hydroxyl radicals [OH] as strong oxidizers. It turned out that the ions of sodium and chlorine are connected into hydrates of sodium hypochlorite NaClO in this case.Keywords
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