Process-based models for nitrogen dynamics in subsurface flow constructed wetlands: A state-of-the-art review

Abstract

In the last two decades, several process-based models had been developed to describe the transport and fate of contaminants in subsurface flow constructed wetlands (SSF CWs) under a variety of conditions. These models have become valuable tools to better design, control and optimize the SSF CW system. Moreover, they can aid investigations on the effects of variables of interest on the system. While excellent review papers on these models have been published, the ability of the existing process-based models in simulating the nitrogen transformations in the SSF CWs have not been highlighted. Consequently, a critical review of the simulation of nitrogen transformation processes is desirable. This paper presents an overview of the available models which are capable of modelling the nitrogen dynamics in the SSF CWs. The existing process-based models can be mainly categorized as the process-dedicated models and Gujer matrix models. A process-dedicated model is a feasible tool for design purposes. Meanwhile, the Gujer matrix model delivers valuable insights into scientific studies. In this paper, the existing models are summarized and critically discussed with regards to their capability and practicality in simulating the nitrogen dynamics in SSF CWs. Organic nitrogen, ammonium, and nitrate are the common nitrogen compounds considered in the process-based models of SSF CWs. Meanwhile, nitrite was frequently considered together with nitrate due to its low concentration in the effluent of SSF CWs. On the other hand, ammonification, nitrification, denitrification, plant uptake and ammonium adsorption are the typical nitrogen transformation and degradation processes found in the existing models, whilst ammonia volatilization was rarely found in the literature. Oxygen and organic matter are the major limiting reactants of nitrogen transformation and degradation processes in the modelling, and other factors such as microbial population, temperature and pH are also considered. The recommendations and future research directions on the influence of microorganism distribution, resting period, oxygen release, ammonium adsorption and plants are outlined.