Aerobic Electrochemical Transformations of DDT to Oxygen-Incorporated Products Catalyzed by a B12 Derivative
- 15 November 2021
- journal article
- research article
- Published by The Chemical Society of Japan in Bulletin of the Chemical Society of Japan
- Vol. 94 (11), 2784-2791
- https://doi.org/10.1246/bcsj.20210316
Abstract
Electrochemical transformations of DDT into oxygen-incorporated products, amides and esters, catalyzed by the B12 derivative, heptamethyl cobyrinate perchlorate, have been developed under aerobic conditions. The dechlorinative oxygenation of DDT formed the acyl chloride as an intermediate for the synthesis of the amide and ester in the reaction with the amine and alcohol, respectively. This electrochemical method demonstrated with 20 oxygen-incorporated dechlorinated products up to 88% yields with 15 new compounds and was also successfully applied to the conversion of methoxychlor to an amide and ester.Keywords
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