Versatile and cost-efficient cleanup of viscous crude oil by an elastic carbon sorbent from direct pyrolysis of a melamine foam
- 13 April 2021
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry A
- Vol. 9 (18), 11268-11277
- https://doi.org/10.1039/d1ta01133b
Abstract
Rational sorbent technology for crude oil cleanup requires the capability of rapid uptake, and a low cost and simple processing method for large-scale manufacturing. Herein, an elastic carbon sorbent can be fabricated through the direct pyrolysis of melamine foam at 1000 ℃ for 2 h. The carbonized melamine foam (CMF) is lightweight (density: 5.4 mg cm-3; porosity>97.2%), superhydrophobic (water contact angle:151±2º), mechanically robust (complete recovery after 80% strain deformation) and highly efficient in crude oil uptake (148.7 g/g crude oil at 60 ℃). More importantly, the CMF has excellent photo- and Joule-thermal conversion efficiency for significantly reducing the viscosity of heavy crude oil under a mild sunlight exposure or a relatively low voltage. These advantages enable CMFs to provide a fast cleanup approach for accidental oil spills under all weather. Continuous oil recovery has also been demonstrated by using a piece of heated CMF and a vacuum pump. Overall, the CMF offers an ideal material solution for addressing the large-scale crude oil cleanup through its versatile and efficient cleanup approaches.Funding Information
- National Natural Science Foundation of China (51203118)
- Fundamental Research Funds for the Central Universities
- Tongji University
- University of Southern Mississippi
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