Determination of excited singlet-state dipole moments of hydroxy and methoxy coumarins using solvatochromic method
Open Access
- 31 March 2012
- journal article
- Published by European Journal of Chemistry in European Journal of Chemistry
- Vol. 3 (1), 75-80
- https://doi.org/10.5155/eurjchem.3.1.75-80.498
Abstract
The effects of solvents of various polarity on the electronic absorption and fluorescence spectra of 7-hydroxy-4-trifluoromethyl coumarin; 6,7-dihydroxy-4-trifluoromethyl coumarin and 7-methoxy-4-trifluoromethyl coumarin have been investigated. The singlet-state excited dipole moments (μe) and ground state dipole moments (μg) are estimated from Bakshiev and Kawski-Chamma-Viallet equations by using the variation of Stokes’ shift with the solvent’s dielectric constant (ε) and refractive index (n). The observed singlet-state excited dipole moments are found to be larger than the ground-state ones. In addition, the geometry and other electronic properties are computed using ab-initio method with correlation functions at 6-31G basis set.Keywords
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