Properties of Zinc Ferrite Nanoparticles Due to PVP Mediation and Annealing at 500°C
Open Access
- 1 January 2019
- journal article
- research article
- Published by Scientific Research Publishing, Inc. in Advances in Nanoparticles
- Vol. 08 (02), 36-45
- https://doi.org/10.4236/anp.2019.82003
Abstract
In contributing to the improvement of Ferrite Magnetic nanoparticles, the effects of Poly (Vinyl Pyrrolidone) (PVP) and annealing on the structural and magnetic properties of Zinc ferrite nanoparticles (ZFNPs) synthesis were investigated in this work. The effects were evaluated using the X-ray diffraction (XRD) spectroscopy, Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and Vi-brating sample magnetometer (VSM). The XRD analysis confirms a good formation of the inverse spinel crystal structure with an average particle size of 1.3 nm to 15.2 nm and from 1.6 nm to 21.1 nm for the ZFNPs as-prepared and PVP mediated ZFNPs for the un-annealed and annealed samples, respectively. The SEM image reveals an increase in the particle size for both the as-prepared and PVP mediated samples after annealing at 500°C. The FTIR also reveals the inverse spinel structure for the as-prepared and annealed samples, which witnesses a vibrational red shift towards a higher wave number for the annealed samples. The VSM analysis indicates the superparamagnetic behavior of PVP mediated and annealed sample with zero remanence magnetization (Mr) and Coercivity (Hc). The saturation magnetization (Ms) increases from 1.31 emu/g, for the as-prepared samples, to 4.31 emu/g after the annealing and from 1.18 emu/g, for the PVP mediated, to 6.38 emu/g after annealing. These effects have been attributed to the cationic re-arrangement on the lattice site after the annealing. This presents a superior material for various applications in nanotechnology.Keywords
This publication has 27 references indexed in Scilit:
- Nano-magnetic particles used in biomedicine: Core and coating materialsMaterials Science and Engineering: C, 2013
- Approximation of crystallite size and microstrain via XRD line broadening analysis in TiSiN thin filmsVacuum, 2012
- Synthesis and characterization of zinc ferrite nanoparticles by a thermal treatment methodSolid State Communications, 2011
- Magnetic and dielectric studies of nanocrystalline zinc substituted Cu–Mn ferritesJournal of Magnetism and Magnetic Materials, 2010
- Magnetic Iron Oxide Nanoparticles: Synthesis and Surface Functionalization StrategiesNanoscale Research Letters, 2008
- Non-stoichiometric zinc-ferrite spinel nanoparticlesJournal of Nanoparticle Research, 2008
- Magnetic Iron Oxide Nanoparticles: Synthesis, Stabilization, Vectorization, Physicochemical Characterizations, and Biological ApplicationsChemical Reviews, 2008
- Functionalisation of magnetic nanoparticles for applications in biomedicineJournal of Physics D: Applied Physics, 2003
- The preparation of magnetic nanoparticles for applications in biomedicineJournal of Physics D: Applied Physics, 2003
- Synthesis and Magnetic Characterization of Zinc Ferrite Nanoparticles with Different Environments: Powder, Colloidal Solution, and Zinc Ferrite−Silica Core−Shell NanoparticlesLangmuir, 2002