Concurrent Structural and Electronic Phase Transitions in V2O3 Thin Films with Sharp Resistivity Change

Abstract

The relationship between structural and electronic phase transitions in V₂O₃ thin films is of critical importance for understanding of the mechanism behind metal–insulator transition (MIT) and related technological applications. Despite being extensively studied, there are currently no clear consensus and picture of the relation between structural and electronic phase transitions so far. Using V₂O₃ thin films grown on r-plane Al₂O₃ substrates, which exhibit abrupt MIT and structural phase transition, we show that the electronic phase transition occurs concurrently with the structural phase transition as revealed by the electrical transport and Raman spectra measurements. Our result provides experimental evidence for clarifying this issue, which could form the basis of theoretical studies as well as technological applications in V₂O₃.