Water-Stable Zero-Dimensional (C4H9)4NCuCl2 Single Crystal with Highly Efficient Broadband Green Emission

Abstract

Here, we report (C₄H₉)₄NCuCl₂ single crystals with a luminous intensity that remains largely the same after soaking in water for 24 h. (CH₉)₄NCuCl₂ has a new type zero-dimensional framework, in which the isolated [CuCl₂]⁻ anions are wrapped by organic (C₄H₉)₄N⁺ cations. As expected, (C₄H₉)₄NCuCl₂ shows a broad emission band at 508 nm with a photoluminescence quantum yield of approximately 82% at room temperature, stemming from self-trapped exciton (STE) emission. Temperature-dependent photoluminescence measurement reveals that there is an energy barrier ΔE (24.0 meV) between the intrinsic state and STE state, which leads to the increase in emission intensity with an increase in temperature (98–278 K), while the emission intensity begins to decrease when the temperature is higher than 278 K due to the effects of both thermal quenching and carrier scattering. Our findings provide a new idea for the design of lead-free anti-water stability metal halide materials.