Biosorption Study of Pb(II) Ions onto Treated Eupatorium adinoforum (AEA) and Acer Oblongum (AAO): Thermodynamic and Equilibrium Studies

Abstract

In the present study, dried activated biomass of Eupatorium adinoforum (AEA) and Acer oblongum (AAO) used for removal of Pb (II) from synthetic wastewater. The batch operation was conducted with effect of variation of contact time, biosorbent dose, pH, concentration of metal ions and temperature on biosorption of metal ions on biosorbent. Maximum adsorption was recorded for initial metal ion concentration of 10 mg/l, biosorbent dose of 2.5 gm, at pH 5 with 105 minutes of contact time for activated AEA and AAO biomass. The adsorption equilibrium conditions were well described by Langmuir, Freundlich and Temkin isotherm models. The Langmuir isotherm model has provided a better fit with the experimental data in comparison to that of Freundlich and Temkin isotherm models. Thermodynamic data suggest that the bisorption process was spontaneous, feasible and endothermic. The values of thermodynamic parameters suggest that the biosorption process was spontaneous, feasible and endothermic. The kinetics of the biosorption for the reaction mechanism and types of biosorption process onto activated AEA and AAO biosorbent were also discussed.