Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
Open Access
- 29 November 2016
- journal article
- Published by Beilstein Institut in Beilstein Journal of Organic Chemistry
- Vol. 12 (1), 2570-2576
- https://doi.org/10.3762/bjoc.12.252
Abstract
Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.Keywords
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